Distribution, characterization, and geochemical controls of elements of concern in uranium mine tailings, Key Lake, Saskatchewan, Canada     

Sean A. Shaw  M. Jim Hendry  Joseph Essilfie-Dughan  Tom Kotzer  Dirk Wallschläger 《Applied Geochemistry》2011,26(12):2044-2056

The distribution of As, Mo, Ni and Se in the aqueous and solid phases of U mine tailings in the Deilmann Tailings Management Facility (DTMF), located at the Key Lake mine in northern Saskatchewan, Canada, was defined using as-discharged tailings samples collected monthly starting in 1996 and core samples collected from the DTMF from 3 locations on 3 occasions between 2004 and 2009. These data indicated that the DTMF can be divided into two geochemical zones; tailings generated from the Deilmann ore body between 1996 and 2000 and tailings from the McArthur River ore body, mined after July 2000. The Deilmann tailings solids are generally characterized by greater elemental concentrations than those in the McArthur River tailings, particularly for As, Co and Ni. These elevated concentrations are attributed to the abundance of Ni–Co–As–S minerals in this ore. The mean aqueous concentrations of As, Mo, Ni, and Se are 3.7, 23.2, 0.14, and 0.02 mg L⁻¹, respectively, in the Deilmann porewaters and 0.20, 4.16, 0.06, and 0.03 mg L⁻¹, respectively, in the McArthur River porewaters. Similarly, the mean As, Mo, Ni, and Se solid phase concentrations are 5.89 × 10³, 69.9, 3.20 × 10³, and 17.4 μg g⁻¹, respectively, for the Deilmann tailings and 440, 13.6, 551, and 3.03 μg g⁻¹ in the McArthur River tailings. Statistically, pH remained unchanged from the time of discharge while Eh values have remained oxic with no significant change between the two tailings types over 15 a of residence time. Results from sequential extractions, thermodynamic modeling, and results of complimentary research indicated that ferrihydrite solubility is the dominant control on aqueous As concentrations and also plays a role in controlling dissolved Mo, Ni and Se.  相似文献   

Sphene and zircon in the Highland Range volcanic sequence (Miocene, southern Nevada, USA): elemental partitioning, phase relations, and influence on evolution of silicic magma   总被引：2，自引：0，他引：2  

Lindy L. Colombini  Calvin F. Miller  Guilherme A. R. Gualda  Joseph L. Wooden  Jonathan S. Miller 《Mineralogy and Petrology》2011,102(1-4):29-50

Sphene is prominent in Miocene plutonic rocks ranging from diorite to granite in southern Nevada, USA, but it is restricted to rhyolites in coeval volcanic sequences. In the Highland Range volcanic sequence, sphene appears as a phenocryst only in the most evolved rocks (72?C77 mass% SiO₂; matrix glass 77?C78 mass% SiO₂). Zr-in-sphene temperatures of crystallization are mostly restricted to 715 and 755°C, in contrast to zircon (710?C920°C, Ti-in-zircon thermometry). Sphene rim/glass Kds for rare earth elements are extremely high (La 120, Sm 1200, Gd 1300, Lu 240). Rare earth elements, especially the middle REE (MREE), decrease from centers to rims of sphene phenocrysts along with Zr, demonstrating the effect of progressive sphene fractionation. Whole rocks and glasses have MREE-depleted, U-shaped REE patterns as a consequence of sphene fractionation. Within the co-genetic, sphene-rich Searchlight pluton, only evolved leucogranites show comparable MREE depletion. These results indicate that sphene saturation in intruded and extruded magmas occurred only in highly evolved melts: abundant sphene in less silicic plutonic rocks represents a late-stage ??bloom?? in fractionated interstitial melt.  相似文献   

Primitive Ordovician (Floian) echinoderms from Sandu,Guizhou Province,South China,and their significance     

Christopher R. C. Paul  Stephen K. Donovan  Lucy A. Muir  Joseph P. Botting  Jih‐Pai Lin  Yuandong Zhang 《Geological Journal》2016,51(1):143-156

Pelmatozoans diversified primarily during the Middle and Late Ordovician Period, with Early Ordovician records being much more limited, resulting in many gaps in our knowledge of the early stages of their diversification. Dissociated pelmatozoan ossicles have been found abundantly in one section in the Tonggao Formation (Tetragraptus approximatus Biozone, Floian, Early Ordovician). Most of the ossicles are thecal plates and stem ossicles from hemicosmitoid and glyptocystitoid cystoids. Thecal plates of ‘Cheirocrinus’ sp., Polycosmites sp., and other plates of uncertain affinity are described. A different ossicle type, Pentagonopentagonalis (col.), may represent crinoid remains; this would be one of the earliest occurrences of the class. The thecal ossicles and columnals are all considered, as both sets of data are desirable to determine the most complete estimate of generic diversity. The echinoderm ossicles may have been transported in from shallower water palaeoenvironments and clusters of ossicles may represent coprolites or regurgitates. Estimates of Early Ordovician palaeogeography that place this site at 30°S or near the palaeoequator are supported by the physiological requirements of the primitive echinoderms described herein. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Glaciation and ~ 770 Ma Ediacara (?) Fossils from the Lesser Karatau Microcontinent,Kazakhstan     

Joseph G. Meert  Anatoly S. Gibsher  Natalia M. Levashova  Warren C. Grice  George D. Kamenov  Alexander B. Ryabinin   《Gondwana Research》2011,19(4):867-880

The Cambrian explosion, c. 530–515 Ma heralded the arrival of a diverse assembly of multicellular life including the first hard-shelled organisms. Fossils found in Cambrian strata represent the ancestors of most modern animal phyla. In contrast to the apparent explosiveness seen in the Cambrian fossil record, studies of molecular biology hint that the diversification observed in Cambrian strata was rooted in ancestry extending back into the Ediacaran (635–542 Ma). Fossil evidence for this mostly cryptic phase of evolution is derived from the soft-bodied fossils of the Ediacaran biota found throughout the world and bilaterian embryos found in the Doushantuo lagerstätte in South China. The first appearance of Ediacara fauna is thought to have followed the last of the ~ 750–635 Ma Neoproterozoic glacial episodes by 20–30 million years. In this paper, we present evidence for the oldest discovery of the ‘Ediacara’ discoidal fossils Nimbia occlusa and Aspidella terranovica (?) that predate the early Cryogenian glaciations by more than fifty million years. There is considerable disagreement over the significance of discoidal Ediacaran fossils, but our findings may support earlier suggestions that metazoan life has roots extending deeper into the Proterozoic Eon. We also confirm the presence of a Late Cryogenian (e.g. “Marinoan”) glaciation on the Lesser Karatau microcontinent including dropstones and striated clasts within the glacial strata.  相似文献   

Excess air during aquifer storage and recovery in an arid basin (Las Vegas Valley, USA)     

D. Kip Solomon  Erin Cole  Joseph F. Leising 《Hydrogeology Journal》2011,19(1):187-194

The Las Vegas Valley Water District in Nevada, USA, has operated an artificial recharge (AR) program since 1989. In summer 2001, observations of gas exsolving from tap water prompted a study that revealed total dissolved gas (TDG) pressures approaching 2?atm with a gas composition that it is predominantly air. Measurements of TDG pressure at well heads and in the distribution system indicated two potential mechanisms for elevated TDG pressures: (1) air entrainment during AR operations, and (2) temperature changes between the winter recharge season and the summer withdrawal season. Air entrainment during pumping was investigated by intentionally allowing the forebay (upstream reservoir) of a large pumping station to drawdown to the point of vortex formation. This resulted in up to a 0.7?atm increase in TDG pressure. In general, the solubility of gases in water decreases as the temperature increases. In the Las Vegas Valley, water that acquired a modest amount of dissolved gas during winter artificial recharge operations experienced an increase in dissolved gas pressure (0.04?atm/°C) as the water warmed in the subsurface. A combination of air entrainment during AR operations and its amplification by temperature increase after recharge can account for most of the observed amounts of excess gas at this site.  相似文献   

The progress on remote sensing technology in identifying tropical forest degradation: a synthesis of the present knowledge and future perspectives     

Shijo Joseph  M. S. R. Murthy  A. P. Thomas 《Environmental Earth Sciences》2011,64(3):731-741

Since the launch of the first satellite in 1972, ecologists have been equipped with new tools to address the degradation of tropical forests, previously limited by field-based methods. This article is a review of the state of remote sensing technology in characterizing the degradation of tropical forest. The factors responsible for the structural and functional degradation of the tropical forest and its likely impacts are described in view of generating remote sensing based inputs. In order to assess the degradation and utility of geo-informatics tools, 32 parameters are identified. The research developments at different levels of information extraction from the historic to recent periods are elaborated, and future challenges are predicted. The article concludes that an additional momentum of research is required to answer many unresolved questions of tropical forest degradation.  相似文献   

On the utility of identification schemes for digital earth science data: an assessment and recommendations   总被引：1，自引：1，他引：0  

Ruth E. Duerr  Robert R. Downs  Curt Tilmes  Bruce Barkstrom  W. Christopher Lenhardt  Joseph Glassy  Luis E. Bermudez  Peter Slaughter 《Earth Science Informatics》2011,4(3):139-160

In recent years, a number of data identification technologies have been developed which purport to permanently identify digital objects. In this paper, nine technologies and systems for assigning persistent identifiers are assessed for their applicability to Earth science data (ARKs, DOIs, XRIs, Handles, LSIDs, OIDs, PURLs, URIs/URNs/URLs, and UUIDs). The evaluation used four use cases that focused on the suitability of each scheme to provide Unique Identifiers for Earth science data objects, to provide Unique Locators for the objects, to serve as Citable Locators, and to uniquely identify the scientific contents of data objects if the data were reformatted. Of all the identifier schemes assessed, the one that most closely meets all of the requirements for an Unique Identifier is the UUID scheme. Any of the URL/URI/IRI-based identifier schemes assessed could be used for Unique Locators. Since there are currently no strong market leaders to help make the choice among them, the decision must be based on secondary criteria. While most publications now allow the use of URLs in citations, so that all of the URL/URI/IRI based identification schemes discussed in this paper could potentially be used as a Citable Locator, DOIs are the identification scheme currently adopted by most commercial publishers. None of the identifier schemes assessed here even minimally address identification of scientifically identical numerical data sets under reformatting.  相似文献   

Climate change links fate of glaciers and an endemic alpine invertebrate     

Clint C. Muhlfeld  J. Joseph Giersch  F. Richard Hauer  Gregory T. Pederson  Gordon Luikart  Douglas P. Peterson  Christopher C. Downs  Daniel B. Fagre 《Climatic change》2011,106(2):337-345

Climate warming in the mid- to high-latitudes and high-elevation mountainous regions is occurring more rapidly than anywhere else on Earth, causing extensive loss of glaciers and snowpack. However, little is known about the effects of climate change on alpine stream biota, especially invertebrates. Here, we show a strong linkage between regional climate change and the fundamental niche of a rare aquatic invertebrate—the meltwater stonefly Lednia tumana—endemic to Waterton-Glacier International Peace Park, Canada and USA. L. tumana has been petitioned for listing under the U.S. Endangered Species Act due to climate-change-induced glacier loss, yet little is known on specifically how climate impacts may threaten this rare species and many other enigmatic alpine aquatic species worldwide. During 14 years of research, we documented that L. tumana inhabits a narrow distribution, restricted to short sections (~500 m) of cold, alpine streams directly below glaciers, permanent snowfields, and springs. Our simulation models suggest that climate change threatens the potential future distribution of these sensitive habitats and the persistence of L. tumana through the loss of glaciers and snowfields. Mountaintop aquatic invertebrates are ideal early warning indicators of climate warming in mountain ecosystems. Research on alpine invertebrates is urgently needed to avoid extinctions and ecosystem change.  相似文献   

Variability in erosion rates related to the state of landscape transience in the semi‐arid Chilean Andes     

Germán Aguilar  Rodrigo Riquelme  Joseph Martinod  José Darrozes  Eric Maire 《地球表面变化过程与地形》2011,36(13):1736-1748

We quantify erosion rates in the higher sectors of the Huasco Valley, in the Main Cordillera of the semi‐arid Andes of Chile, using elevation differences between three successive geomorphic markers (pediments and paleo‐valleys) and the present day valley. Available Ar‐Ar ages of Neogene pediments are used to estimate mean erosion rates for the three periods (16 to 13 My, 13 to 8 My, and following 8 My). The landscape of the Huasco Valley is in a transient state, as indicated by well‐preserved pediment surfaces in interfluves, valleys deeply incised by fluvial and glacial erosion and scarped head‐valleys that represent the current knickzones. Higher erosion rates (45–75 m/My) are calculated for the more recent period (< 8 My) during which deep incision developed compared to previous periods (6–31 m/My). Quantitative data indicate that glaciers had a much higher erosional capability than fluvial activity in the higher sectors of the Main Cordillera. Comparison with erosion rates calculated in other drainage basins of the Chilean Andes suggests that the variability of erosion rates depends on the landscape's transient erosive state. The landscape's geomorphologic response to the uplift of the Main Cordillera results in the retreat of a knickzone, for which retreat velocity depends on precipitation rate pattern and glacial erosion intensity. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

A method to regenerate the damaged Chironomidae slides in entellan mounting solution     

Armin Namayandeh  Joseph Culp 《Journal of Paleolimnology》2015,53(2):251-253

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